42-4 Alpha Decay#
Prompts
What is an alpha particle? Write the general alpha-decay equation and identify parent, daughter, and the alpha.
Define the decay energy \(Q\). How do you calculate \(Q\) from atomic masses? Why must \(Q > 0\) for decay to occur?
Classically, an alpha particle inside the nucleus has energy less than the Coulomb barrier height. Why doesn’t it stay trapped? Explain quantum tunneling in this context.
The alpha and the daughter nucleus share the kinetic energy \(Q\). Which gets more — and why?
Why do alpha emitters with higher \(Q\) typically have shorter half-lives?
Lecture Notes#
Overview#
Alpha decay is the emission of an alpha particle — a \(^4\text{He}\) nucleus (2 protons, 2 neutrons) — from a heavy nucleus. The parent becomes a lighter daughter nucleus.
The decay energy \(Q\) is the total kinetic energy released; it equals the mass defect times \(c^2\). Conservation of momentum determines how \(Q\) is shared between the alpha and the daughter.
Quantum tunneling through the Coulomb barrier explains why alpha particles can escape even when their kinetic energy is less than the barrier height — a purely classical picture would forbid the decay.
Alpha Decay and the Alpha Particle#
An alpha particle (\(\alpha\)) is a \(^4\text{He}\) nucleus: \(Z = 2\), \(N = 2\), \(A = 4\). It is a tightly bound cluster (high binding energy per nucleon) and is emitted as a unit.
The general alpha-decay reaction is
Example: \(^{238}\text{U} \to ^{234}\text{Th} + \alpha\). Alpha decay occurs mainly for heavy nuclei (\(A \gtrsim 150\)) where the Coulomb repulsion among protons makes emission energetically favorable.
Decay Energy (Q-Value)#
The decay energy \(Q\) is the total kinetic energy released in the decay. By conservation of energy:
where the masses are nuclear masses (or atomic masses; the electron masses cancel in the difference). For decay to be possible, we need \(Q > 0\) — the parent must be heavier than the sum of the products.
Using atomic masses
When using atomic masses, the \(Z\) electrons on the parent cancel with \((Z-2)\) on the daughter plus 2 on the alpha (as \(^4\text{He}\) atom). The same \(Q\) results.
Energy sharing: The alpha and daughter are emitted back-to-back (conservation of momentum). The lighter alpha carries most of the kinetic energy. In the nonrelativistic limit:
For \(^{238}\text{U}\), \(K_\alpha \approx 0.98\,Q\) — the alpha gets nearly all of \(Q\).
Quantum Tunneling Through the Coulomb Barrier#
Inside the nucleus, the alpha feels the strong force (attractive, short range) and the Coulomb repulsion (repulsive, long range) from the daughter. Outside, only Coulomb remains. The potential has a barrier: the alpha must overcome Coulomb repulsion to escape.
Classically, if the alpha’s kinetic energy \(E\) is less than the barrier height, it cannot escape. Yet alpha decay occurs with \(E < E_{\text{barrier}}\). The explanation is quantum tunneling (section 38-9): the alpha has a nonzero probability to “tunnel” through the classically forbidden region.
Higher \(Q\) → alpha has more energy → tunneling probability increases → shorter half-life.
Lower \(Q\) → alpha has less energy → tunneling is less likely → longer half-life.
This Geiger–Nuttall relationship (half-life vs. alpha energy) was observed empirically before quantum mechanics; tunneling provides the theoretical basis.
Why alpha and not single nucleons?
An alpha is very tightly bound; ejecting a single proton or neutron would require more energy (the nucleus would have to break a strong bond). Alpha emission is favored when the mass of (daughter + alpha) is less than the parent — a condition met for many heavy nuclei.
Summary#
Alpha particle: \(^4\text{He}\) nucleus; alpha decay: parent \(\to\) daughter \(+ \alpha\).
Decay energy: \(Q = (M_{\text{parent}} - M_{\text{daughter}} - M_\alpha)c^2\); \(Q > 0\) required.
Alpha carries most of \(K\) (lighter particle); \(K_\alpha \approx \frac{A-4}{A}Q\).
Quantum tunneling through the Coulomb barrier explains escape when \(E < E_{\text{barrier}}\).
Higher \(Q\) → shorter half-life (Geiger–Nuttall).